• 找产品
  • 查百科

    400-133-2688

    客服热线(工作日:9:00-17:30)

33252-29-8

2-氯-6-氰基吡啶,97%

产品编号: R000067 CAS号: 33252-29-8
分子式: C6H3ClN2 分子量: 138.56
MDL号: MFCD00274527
货号 库存 目录价(¥) 优惠价(¥) 购买
R000067-1g
  
4~8周 610 610  
R000067-5g
  
4~8周 1822 1822  

化学品安全技术说明书

产品名称: 2-氯-6-氰基吡啶 按照GB/T 16483、GB/T 17519 编制
修订日期: 2018年02月03日 最初编制日期: 2018年02月03日
版本: 1.0

第1部分 化学品及企业标识

化学品中文名: 2-氯-6-氰基吡啶
化学品英文名: 6-chloropyridine-2-carbonitrile
产品编号: -
企业名称: 上海凛恩科技发展有限公司
企业地址: 上海市奉贤化工区楚华支路429号
邮 编: 201417
传真: 021-57461626
联系电话: 4001332688
电子邮件地址: sales@rhawn.cn
企业应急电话: 4001332688(24h)
产品推荐及限制用途: For industry use only.。

第2部分 危险性概述

紧急情况概述:

吞咽会中毒。造成皮肤刺激。造成严重眼损伤。可引起呼吸道刺激。可引起昏睡或眩晕。

GHS危险性类别:

急性经口毒性 类别 3

皮肤腐蚀 / 刺激 类别 2

严重眼损伤 / 眼刺激 类别 1

特异性靶器官毒性 一次接触 类别 3

标签要素:

象形图:
警示词: 危险

危险性说明:

H301 吞咽会中毒。

H315 造成皮肤刺激。

H318 造成严重眼损伤。

H335 可引起呼吸道刺激。

H336 可引起昏睡或眩晕。

防范说明:

  • 预防措施:

    —— P264 作业后彻底清洗。

    —— P270 使用本产品时不要进食、饮 水或吸烟。

    —— P280 戴防护手套/穿防护服/戴防 护眼罩/戴防护面具。

    —— P261 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。

    —— P271 只能在室外或通风良好处使 用。

  • 事故响应:

    —— P301+P310 如误吞咽: 立即呼叫解毒中心/医生

    —— P321 具体治疗 ( 见本标签上的…… )。

    —— P330 漱口。

    —— P302+P352 如皮肤沾染: 用水充分清洗。

    —— P332+P313 如发生皮肤刺激: 求医/就诊。

    —— P362+P364 脱掉沾染的衣服,清洗后方可 重新使用

    —— P305+P351+P338 如进入眼睛: 用水小心冲洗几分钟。如戴隐 形眼镜并可方便地取出,取出 隐形眼镜。继续冲洗。

    —— P310 立即呼叫解毒中心/医生

    —— P304+P340 如误吸入: 将人转移到空气新鲜处,保持 呼吸舒适体位。

    —— P312 如感觉不适,呼叫解毒中心/医生

  • 安全储存:

    —— P405 存放处须加锁。

    —— P403+P233 存放在通风良好的地方。保 持容器密闭。

  • 废弃处置:

    —— P501 按当地法规处置内装物/容器。

物理和化学危险: 无资料
健康危害: 吞咽会中毒。造成皮肤刺激。造成严重眼损伤。可引起呼吸道刺激。可引起昏睡或眩晕。
环境危害: 无资料

第3部分 成分/组成信息

组分 浓度或浓度范围(质量分数,%) CAS No.
6-chloropyridine-2-carbonitrile 100% 33252-29-8

第4部分 急救措施

急 救:

吸 入: 如果吸入,请将患者移到新鲜空气处。
皮肤接触: 脱去污染的衣着,用肥皂水和清水彻底冲洗皮肤。如有不适感,就医。
眼晴接触: 分开眼睑,用流动清水或生理盐水冲洗。立即就医。
食 入: 漱口,禁止催吐。立即就医。
对保护施救者的忠告: 将患者转移到安全的场所。咨询医生。出示此化学品安全技术说明书给到现场的医生看。
对医生的特别提示: 无资料。

第5部分 消防措施

灭火剂:

用水雾、干粉、泡沫或二氧化碳灭火剂灭火。

避免使用直流水灭火,直流水可能导致可燃性液体的飞溅,使火势扩散。

特别危险性:

无资料。

灭火注意事项及防护措施:

消防人员须佩戴携气式呼吸器,穿全身消防服,在上风向灭火。

尽可能将容器从火场移至空旷处。

处在火场中的容器若已变色或从安全泄压装置中发出声音,必须马上撤离。

隔离事故现场,禁止无关人员进入。收容和处理消防水,防止污染环境。

第6部分 泄露应急处理

作业人员防护措施、防护装备和应急处置程序:

建议应急处理人员戴携气式呼吸器,穿防静电服,戴橡胶耐油手套。

禁止接触或跨越泄漏物。

作业时使用的所有设备应接地。

尽可能切断泄漏源。

消除所有点火源。

根据液体流动、蒸汽或粉尘扩散的影响区域划定警戒区,无关人员从侧风、上风向撤离至安全区。

环境保护措施: 收容泄漏物,避免污染环境。防止泄漏物进入下水道、地表水和地下水。

泄漏化学品的收容、清除方法及所使用的处置材料:

小量泄漏:尽可能将泄漏液体收集在可密闭的容器中。用沙土、活性炭或其它惰性材料吸收,并转移至安全场所。禁止冲入下水道。

大量泄漏:构筑围堤或挖坑收容。封闭排水管道。用泡沫覆盖,抑制蒸发。用防爆泵转移至槽车或专用收集器内,回收或运至废物处理场所处置。

第7部分 操作处置与储存

操作注意事项:

操作人员应经过专门培训,严格遵守操作规程。

操作处置应在具备局部通风或全面通风换气设施的场所进行。

避免眼和皮肤的接触,避免吸入蒸汽。

个体防护措施参见第8部分。

远离火种、热源,工作场所严禁吸烟。

使用防爆型的通风系统和设备。

如需罐装,应控制流速,且有接地装置,防止静电积聚。

避免与氧化剂等禁配物接触(禁配物参见第10部分)。

搬运时要轻装轻卸,防止包装及容器损坏。

倒空的容器可能残留有害物。

使用后洗手,禁止在工作场所进饮食。

配备相应品种和数量的消防器材及泄漏应急处理设备。

储存注意事项:

储存于阴凉、通风的库房。

库温不宜超过37°C。

应与氧化剂、食用化学品分开存放,切忌混储(禁配物参见第10部分)。

保持容器密封。

远离火种、热源。

库房必须安装避雷设备。

排风系统应设有导除静电的接地装置。

采用防爆型照明、通风设置。

禁止使用易产生火花的设备和工具。

储区应备有泄漏应急处理设备和合适的收容材料。


SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Feb. 3, 2018

Revision Date: Feb. 3, 2018

1.Identification

1.1 GHS Product identifier

Product name 6-chloropyridine-2-carbonitrile

1.2 Other means of identification

Product number -
Other names 6-Chloropicolinonitrile

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

Company Shanghai Rhawn Technology Development Co. Ltd.
Address No. 429, Chu Hua Branch, Fengxian Chemical District, Shanghai
Telephone 4001332688
Fax 021-57461626

1.5 Emergency phone number

Emergency phone number 4001332688
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2. Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 3

Skin irritation, Category 2

Serious eye damage, Category 1

Specific target organ toxicity – single exposure, Category 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H301 Toxic if swallowed

H315 Causes skin irritation

H318 Causes serious eye damage

H335 May cause respiratory irritation

H336 May cause drowsiness or dizziness

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

Response

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

P321 Specific treatment (see ... on this label).

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER/doctor/…

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER/doctor/…if you feel unwell.

Storage

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

2.3 Other hazards which do not result in classification

no data available

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
6-chloropyridine-2-carbonitrile 6-chloropyridine-2-carbonitrile 33252-29-8 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Medical attention is required. Consult a doctor. Show this safety data sheet (SDS) to the doctor in attendance.

If inhaled

Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

Following skin contact

Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

Following eye contact

Rinse with pure water for at least 15 minutes. Consult a doctor.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

4.2 Most important symptoms/effects, acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed, if necessary

no data available

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.

5.2 Specific hazards arising from the chemical

no data available

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing mist, gas or vapours. Avoid contacting with skin and eye. Use personal protective equipment. Wear chemical impermeable gloves. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

6.2 Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

7.Handling and storage

7.1 Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

7.2 Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.